Ozone / O₃

Ozone

Gas Identification

Other denomination

Trioxygen

CAS Registry Number
10028-15-6
SCBA type
ABEK Hg P3

Chemical properties

Molecular formula
O₃
Molecular mass
48 g/mol

Physical properties

Boiling point
-111,9 °C
Autoignition temperature
ininflammable
Gas/Vapour density
1,66
IP
12,43 eV

Flammability limit

LFL
-
UFL
-

Threshold limit value

TLV-TWA
0,1 ppm • 0,2 mg/m³
TLV-STEL
0,2 ppm • 0,4 mg/m³

Ozone : Description and use

Description

Ozone is a normal component in the atmosphere. Its concentration varies with altitude, latitude, temperature, solar radiation and air pollution. It is continuously being formed in the upper atmosphere due to the
photochemical effect of ultraviolet rays at wavelengths of under 250nm on the oxygen in the air. In the stratosphere, at an altitude of 15 to 50km, the concentration of ozone is approximately 1 to 10ppm and makes up what we call the ozone layer; the Earth's shield against ultraviolet rays. The usual concentration in the environment at ground level varies between 0.005 and 0.05ppm. As an air pollutant, ozone is identified both as a greenhouse gas (contributing around 8%) and one of the gases comprising smog. It is linked with the formation and decomposition of nitrogen oxides, which are a product of using fossil fuels.
At ambient temperature, it is a pale blue gas, or even colourless, which is characterised by its odour.

Flammability: Ozone is a non-flammable gas. However, it is a powerful oxidising agent which could start a fire.
Explosiveness: The decomposition of ozone can be explosive: ozone in liquid or solid state and the gaseous mixtures of concentrated ozone in oxygen (over 9.2% vol/vol) can explode further to an impact or if they are exposed to heat, a spark, sudden temperature or pressure changes or in the presence of impurities. Its reaction with certain compounds, including flammable materials, combustibles and oxidisable materials, can be violent and can cause an explosion.

USE

Ozone is mainly used in water treatment to:

  • disinfect municipal sewer water to destroy pollutants such as cyanides and phenols in industrial waste water
  • treat drinking water, water for bottling and the water used in many industrial processes (water in cooling towers, rinsing water in the food industry, etc.)
  • deodorise the water used to produce beer and drinks
  • disinfect pool and spa water > to sterilise surgical instruments

In various industrial processes, it is mainly used for its oxidising properties:

  • in the synthesis of many organic products, including acids, aldehydes or ketones, using fatty acids or steroids
  • for bleaching waxes, oils, textile fibres and paper pulp
  • in the pharmaceutical sector to produce peroxides used as germicides in topical lotions
  • as ozonated water to oxidise organic materials on the surface of electronic components
  • to reduce the concentration of chlorine impurities in nitric acid

Ozone : Warnings and caution

GHS hazard statements

H270 - May cause or intensify fire; oxidiser.
H330 - Fatal if inhaled.
H341 - Suspected of causing genetic defects.
H370 - Causes serious damage to organs.
H335 - May cause respiratory irritation.
H372 - Causes damage to organs through prolonged or repeated exposure; Can explode further to a shock and/or friction.

SGH06 : Toxique
SGH03 : Comburant
SGH08 : Sensibilisant, mutagène, cancérogène, reprotoxique
SGH07 : Toxique, irritant, sensibilisant, narcotique